Physics of EtaPrime->Pi+Pi-Eta and EtaPrime->Pi+Pi-Pi0 decays

The article describes experimental status of EtaPrime->Pi+Pi-Eta and EtaPrime->Pi+Pi-Pi0 decays. A theoretical framework used for description of the decays mechanism is also reviewed. The possibilities for the measurements with WASA-at-COSY are mentioned.Comment: Proceedings from Symposium on Meson Physics at COSY-11 and WASA-at-COSY, Cracow, 17-22 June 200

Luminosity determination for the quasi-free nuclear reactions

A method for the calculation of the luminosity for the proton-nucleus collisions based on the quasi-free proton-proton scattering is presented. As an example of application the integrated luminosity for the scattering of protons off the deuteron target is determined for the experiment of the quasi-free pn --> pneta reaction performed by means of the COSY-11 facility.Comment: 7 pages, 5 figures, Presented at Symposium on Meson Physics at COSY-11 and WASA-at-COSY, Cracow, Poland, 17-22 Jun 200

Experimental Test of Momentum Cooling Model Predictions at COSY and Conclusions for WASA and HESR

The High-Energy Storage Ring (HESR) of the future International Facility for Antiproton and Ion Research (FAIR) at GSI in Darmstadt is planned as an anti-proton cooler ring in the momentum range from 1.5 to 15 GeV/c. An important and challenging feature of the new facility is the combination of highly dense phase space cooled beams with internal targets. A detailed numerical and analytical approach to the Fokker-Planck equation for longitudinal filter cooling including the beam - target interaction has been carried out to demonstrate the stochastic cooling capability. To gain confidence in the model predictions a series of experimental stochastic cooling studies with the internal target ANKE at COSY have been carried out. A remarkable agreement between model and experiment was achieved. On this basis longitudinal stochastic cooling simulations were performed to predict the possibilities and limits of cooling when the newly installed WASA Pellet-target is operated.Comment: 17 pages, 11 figures, Talk given at Symposium on Meson Physics at COSY-11 and WASA-at-COSY, Cracow, Poland, 17-22 Jun 200

Academic attainment and special educational needs in extremely preterm children at 11 years of age : the EPICure Study

Aim: To assess academic attainment and special educational needs (SEN) in extremely preterm (EP) children in middle childhood. Methods: Of 307 EP (=25 weeks) survivors born in the UK and Ireland in 1995, 219 (71%) were re-assessed at 11 years, with a comparison group of 153 classmates born at term, using standardised tests of cognitive ability and academic attainment and teacher reports of school performance and special educational needs (SEN). Multiple imputation was used to correct for selective dropout. Results: EP children had significantly lower scores than classmates for cognitive ability (-20 points; 95%CI: -23,-17), reading (-18 points; -22,-15) and mathematics (-27 points; -31,-23). Twenty-nine (13%) EP children attended special school. In mainstream schools, 105 (57%) EP children had SEN (OR: 10; 6, 18) and 103 (55%) required SEN resource provision (OR: 10; 5, 18). Teachers rated 50% of EP children with attainment below the average range compared with 5% of classmates (OR: 18; CI: 8, 41). EP children who are entered for mainstream education an academic year early due to preterm birth had similar academic attainment but required more SEN support (OR: 2; 1.1,3.8). Conclusions: EP survivors remain at high risk for learning impairments and poor academic attainment in middle childhood. A significant proportion require full-time specialist education and over half of those attending mainstream schools require additional health or educational resources in order to access the national curriculum. The prevalence and impact of SEN is likely to increase as these children approach the transition to secondary school. -------------------------------------------------------------------------------

Pathways between childhood victimization and psychosis-like symptoms in the ALSPAC Birth Cohort

Background: Several large population-based studies have demonstrated associations between adverse childhood experiences and later development of psychotic symptoms. However, little attention has been paid to the mechanisms involved in this pathway and the few existing studies have relied on cross-sectional assessments. Methods: Prospective data on 6692 children from the UK Avon Longitudinal Study of Parents and Children (ALSPAC) were used to address this issue. Mothers reported on children’s exposure to harsh parenting and domestic violence in early childhood, and children self-reported on bullying victimization prior to 8.5 years. Presence of children’s anxiety at 10 years and their depressive symptoms at 9 and 11 years were ascertained from mothers, and children completed assessments of self-esteem and locus of control at 8.5 years. Children were interviewed regarding psychotic symptoms at a mean age of 12.9 years. Multiple mediation analysis was performed to examine direct and indirect effects of each childhood adversity on psychotic symptoms. Results: The association between harsh parenting and psychotic symptoms was fully mediated by anxiety, depressive symptoms, external locus of control, and low self-esteem. Bullying victimization and exposure to domestic violence had their associations with psychotic symptoms partially mediated by anxiety, depression, locus of control, and self-esteem. Similar results were obtained following adjustment for a range of confounders and when analyses were conducted for boys and girls separately. Conclusions: These findings tentatively suggest that specific cognitive and affective difficulties in childhood could be targeted to minimize the likelihood of adolescents exposed to early trauma from developing psychotic symptoms

Modelling multiphase chemistry in deliquescent aerosols and clouds using CAPRAM3.0i

Modelling studies were performed with the multiphase mechanism RACM- MIM2ext/CAPRAM 3.0i to investigate the tropospheric multiphase chemistry in deli- quesced particles and non-precipitating clouds using the SPACCIM model framework. Simulations using a non-permanent cloud scenario were carried out for two different environmental conditions focusing on the multiphase chemistry of oxidants and other linked chemical subsystems. Model results were analysed by time-resolved reaction flux analyses allowing advanced interpretations. The model shows significant effects of multiphase chemical interactions on the tropospheric budget of gas-phase oxidants and organic com- pounds. In-cloud gas-phase OH radical concentration reductions of about 90 % and 75 % were modelled for urban and remote conditions, respectively. The reduced in-cloud gas- phase oxidation budget increases the tropospheric residence time of organic trace gases by up to about 30 %. Aqueous-phase oxidations of methylglyoxal and 1,4-butenedial were identified as important OH radical sinks under polluted conditions. The model revealed that the organic C3 and C4 chemistry contributes with about 38 %/48 % and 8 %/9 % consid- erably to the urban and remote cloud / aqueous particle OH sinks. Furthermore, the simulations clearly implicate the potential role of deliquescent particles to operate as a reactive chemical medium due to an efficient TMI/HOx,y chemical processing including e.g. an effective in-situ formation of OH radicals. Considerable chemical differences be- tween deliquescent particles and cloud droplets, e.g. a circa 2 times more efficient daytime iron processing in the urban deliquescent particles, were identified. The in-cloud oxidation of methylglyoxal and its oxidation products is identified as efficient sink for NO3 radicals in the aqueous phase

Implementation of multirate time integration methods for air pollution modelling

Explicit time integration methods are characterised by a small numerical effort per time step. In the application to multiscale problems in atmospheric modelling, this benefit is often more than compensated by stability problems and step size restrictions resulting from stiff chemical reaction terms and from a locally varying Courant-Friedrichs-Lewy (CFL) condition for the advection terms. Splitting methods may be applied to efficiently combine implicit and explicit methods (IMEX splitting). Complementarily multirate time integration schemes allow for a local adaptation of the time step size to the grid size. In combination, these approaches lead to schemes which are efficient in terms of evaluations of the right-hand side. Special challenges arise when these methods are to be implemented. For an efficient implementation, it is crucial to locate and exploit redundancies. Furthermore, the more complex programme flow may lead to computational overhead which, in the worst case, more than compensates the theoretical gain in efficiency. We present a general splitting approach which allows both for IMEX splittings and for local time step adaptation. The main focus is on an efficient implementation of this approach for parallel computation on computer clusters

Treatment of non-ideality in the SPACCIM multiphase model – Part 1: Model development

Ambient tropospheric deliquesced particles generally comprise a complex mixture of electrolytes, organic compounds, and water. Dynamic modeling of physical and chemical processes in this complex matrix is challenging. Thus, up-to-date multiphase chemistry models generally do not consider non-ideal solution effects. Therefore, the present study was aimed at presenting further development of the SPACCIM (Spectral Aerosol Cloud Chemistry Interaction Model) through treatment of solution non-ideality, which has not been considered before. The present paper firstly describes the model developments including (i) the implementation of solution non-ideality in aqueous-phase reaction kinetics in the SPACCIM framework, (ii) the advancements in the coupling scheme of microphysics and multiphase chemistry and (iii) the required adjustments of the numerical schemes, especially in the sparse linear solver and the calculation of the Jacobian. Secondly, results of sensitivity investigations are outlined, aiming at the evaluation of different activity coefficient modules and the examination of the contributions of different intermolecular forces to the overall activity coefficients. Finally, first results obtained with the new model framework are presented. The SPACCIM parcel model was developed and, so far, applied for the description of aerosol–cloud interactions. To advance SPACCIM also for modeling physical and chemical processes in deliquesced particles, the solution non-ideality has to be taken into account by utilizing activities in reaction terms instead of aqueous concentrations. The main goal of the extended approach was to provide appropriate activity coefficients for solved species. Therefore, an activity coefficient module was incorporated into the kinetic model framework of SPACCIM. Based on an intercomparison of different activity coefficient models and the comparison with experimental data, the AIOMFAC approach was implemented and extended by additional interaction parameters from the literature for mixed organic–inorganic systems. Moreover, the performance and the capability of the applied activity coefficient module were evaluated by means of water activity measurements, literature data and results of other activity coefficient models. Comprehensive comparison studies showed that the SpactMod (SPACCIM activity coefficient module) is valuable for predicting the thermodynamic behavior of complex mixtures of multicomponent atmospheric aerosol particles. First simulations with a detailed chemical mechanism have demonstrated the applicability of SPACCIM-SpactMod. The simulations indicate that the treatment of solution non-ideality might be needed for modeling multiphase chemistry processes in deliquesced particles. The modeled activity coefficients imply that chemical reaction fluxes of chemical processes in deliquesced particles can be both decreased and increased depending on the particular species involved in the reactions. For key ions, activity coefficients on the order of 0.1–0.8 and a strong dependency on the charge state as well as the RH conditions are modeled, implying a lowered chemical processing of ions in concentrated solutions. In contrast, modeled activity coefficients of organic compounds are in some cases larger than 1 under deliquesced particle conditions and suggest the possibility of an increased chemical processing of organic compounds. Moreover, the model runs have shown noticeable differences in the pH values calculated with and without consideration of solution non-ideality. On average, the predicted pH values of the simulations considering solution non-ideality are -0.27 and -0.44 pH units lower under 90 and 70%RH con- ditions, respectively. More comprehensive results of detailed SPACCIM-SpactMod studies on the multiphase processing in organic–inorganic mixtures of deliquesced particles are described in a companion paper